Research Progress and Prospect of Micro Arc Oxidation Surface Treatment Technology for Magnesium Alloys
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摘要: 镁合金具有的独特性能已在汽车、航空、航天、电子、兵工等领域广泛应用,但其极易腐蚀的缺点给设备的安全、稳定运行带来潜在的危险,甚至造成重大经济损失。本文从微弧氧化技术的研究现状着手,重点讨论了电解液体系、电参数、氧化时间、添加剂等对镁合金陶瓷膜性能的影响,进而分析了微弧氧化陶瓷膜的组成、结构特征和形成过程,并提出了镁合金微弧氧化的发展方向。
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图 1 微弧氧化装置示意图[10]
图 2 微弧氧化技术发展历程图[12]
图 3 微弧氧化过程电流-电压关系[14]
图 4 微弧氧化过程示意图[27]
图 5 AZ91D合金微弧氧化膜层的形貌[37]
图 6 正常膜层与破坏膜层表面的SEM图[44]
图 7 不同脉冲频率下所得MAO膜的表面形貌[46]
图 8 微弧氧化膜层的微观形貌[72]
图 9 AZ31微弧氧化涂层[74]
表 1 微弧氧化与阳极氧化技术比较
氧化
工艺电压电流 工艺流程 处理时间/
min最大膜层厚度/mm 工作
温度/℃氧化处理 膜层均匀性 氧化膜相结构 5%盐雾腐蚀/h 硬度/HV 孔隙率/% 微弧氧化 高压、电流密度大 易于操作 10~30 200~300 <45 化学氧化、电化学氧化等 内外表面均匀 晶态
氧化物>1000 500~
30000~40 阳极氧化 低压、电流密度小 较为复杂 60~120 50~80 50~80 化学氧化、电化学氧化等 尖角类缺陷 无定形相 >300 300~
500>40 -
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