Unveiling High-Entropy Alloy Nanomaterials: A Quantum Leap in Catalysis
-
摘要: 高熵合金是一种由5种或更多的金属元素以相等或接近相等的比例组成的新型合金，具有灵活可调的多元化结构和潜在的特性。随着合成技术的不断进步，让可控合成纳米尺度的高熵合金成为现实，因其独特的微观结构、优异的热稳定性，高熵合金纳米材料在电/热催化和清洁能源转换等方面表现出巨大应用潜力。本文主要介绍对高熵合金纳米材料的基本见解、先进的合成和表征技术并讨论其催化应用。
-
[1] Yeh J W, Chen S K, Lin S J, et al. Nanostructured high-entropy alloys with multiple principal elements: novel alloy design concepts and outcomes. Adv Eng Mater, 2004, 6(5): 299 doi: 10.1002/adem.200300567 [2] Yao Y G, Dong Q, Brozena A, et al. High-entropy nanoparticles: synthesis-structure-property relationships and data-driven discovery. Science, 2022, 376(6589): 151 [3] George E P, Raabe D, Ritchie R O. High-entropy alloys. Nat Rev Mater, 2019, 4(8): 515 doi: 10.1038/s41578-019-0121-4 [4] Mori K, Hashimoto N, Kamiuchi N, et al. Hydrogen spillover-driven synthesis of high-entropy alloy nanoparticles as a robust catalyst for CO2 hydrogenation. Nat Commun, 2021, 12(1): 3884 doi: 10.1038/s41467-021-24228-z [5] Song B A, Yang Y, Rabbani M, et al. In Situ oxidation studies of high-entropy alloy nanoparticles. ACS Nano, 2020, 14(11): 15131 doi: 10.1021/acsnano.0c05250 [6] Chen X F, Wang Q, Cheng Z Y, et al. Direct observation of chemical short-range order in a medium-entropy alloy. Nature, 2021, 592(7856): 712 doi: 10.1038/s41586-021-03428-z [7] Yao Y G, Huang Z N, Xie P F, et al. Carbothermal shock synthesis of high-entropy-alloy nanoparticles. Science, 2018, 359(6383): 1489 doi: 10.1126/science.aan5412 [8] Qiao H Y, Saray M T, Wang X Z, et al. Scalable synthesis of high entropy alloy nanoparticles by microwave heating. ACS Nano, 2021, 15(9): 14928 doi: 10.1021/acsnano.1c05113 [9] Zhan C H, Xu Y, Bu L Z, et al. Subnanometer high-entropy alloy nanowires enable remarkable hydrogen oxidation catalysis. Nat Commun, 2021, 12(1): 6261 doi: 10.1038/s41467-021-26425-2 [10] Löffler T, Meyer H, Savan A, et al. Discovery of a multinary noble metal-free oxygen reduction catalyst. Adv Eng Mater, 2018, 8(34): Art No. 1802269 [11] Nellaiappan S, Katiyar N K, Kumar R, et al. High-entropy alloys as catalysts for the CO2 and CO reduction reactions: experimental realization. ACS Catal, 2020, 10(6): 3658 doi: 10.1021/acscatal.9b04302 [12] Feng G, Ning F H, Song J, et al. Sub-2 nm ultrasmall high-entropy alloy nanoparticles for extremely superior electrocatalytic hydrogen evolution. J Am Chem Soc, 2021, 143(41): 17117 doi: 10.1021/jacs.1c07643 [13] Li H D, Lai J P, Li Z J, et al. Multi-sites electrocatalysis in high-entropy alloys. Adv Funct Mater, 2021, 31(47): Art No. 2106715 [14] Xie P F, Yao Y G, Huang Z N, et al. Highly efficient decomposition of ammonia using high-entropy alloy catalysts. Nat Commun, 2019, 10(1): 4011 doi: 10.1038/s41467-019-11848-9 -
下载:
点击查看大图
图(14)
计量
- 文章访问数: 1263
- HTML全文浏览量: 53
- PDF下载量: 45
- 被引次数: 0
